Organic Chemistry Frontiers · 2022 · 16 citations · 34 references
Natural SciencesChemistryCatalysisOrganic ChemistryPhotocatalysisPhotochemical SynthesisPhotochemistryRadical ReactionsReaction MechanismsCopper CatalysisRegioselectivity
The synthesis of allenyl nitriles was realized through the combination of photoinduced C–O bond cleavage and copper catalysis. Both 1,3-disubstituted and trisubstituted allenyl nitriles were accessed with good yields and high regioselectivity.
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Christopher C. Nawrat, Christopher R. Jamison, Yuriy Slutskyy et al. · Journal of the American Chemical Society · 2015 · 404 citations