Concepedia

Isolating elusive ‘Al(μ-O)M’ intermediates in CO<sub>2</sub>reduction by bimetallic Al–M complexes (M = Zn, Mg)

Matthew J. Evans, George H. Iliffe, Samuel E. Neale, Claire L. McMullin, J. Robin Fulton, Mathew D. Anker, Martyn P. Coles

Chemical Communications · 2022 · 36 citations · 28 references

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Abstract

We confirm that the μ-oxo species (NON Dipp )Al(μ-O)M(BDI Mes ) are viable intermediates in the conversion of CO 2 to carbonate promoted by bimetallic Al–Mg and Al–Zn compounds.

References

28

Bader’s Theory of Atoms in Molecules (AIM) and its Applications to Chemical Bonding

P. Shyam Vinod Kumar, V Raghavendra, V. Subramanian · Journal of Chemical Sciences · 2016 · 626 citations

, , +14

The coordination chemistry of carbon dioxide and its relevance for catalysis: a critical survey

Walter Leitner · Coordination Chemistry Reviews · 1996 · 536 citations

, , +15

Recent developments in the activation of carbon dioxide by metal complexes

Xiaolong Yin, John R. Moss · Coordination Chemistry Reviews · 1999 · 517 citations

, , +12

β‐Diketiminate‐Stabilized Magnesium(I) Dimers and Magnesium(II) Hydride Complexes: Synthesis, Characterization, Adduct Formation, and Reactivity Studies

S.J. Bonyhady, Cameron Jones, Sharanappa Nembenna et al. · Chemistry - A European Journal · 2009 · 449 citations

, , +17

Synthesis, structure and reaction chemistry of a nucleophilic aluminyl anion

Jamie Hicks, Petra Vasko, José M. Goicoechea et al. · Nature · 2018 · 378 citations · Full text

, , +8