Concepedia

Organic carboxylate salt-enabled alternative synthetic routes for bio-functional cyclic carbonates and aliphatic polycarbonates

Yuya Watanabe, Shunya Takaoka, Yuta Haga, Kohei Kishi, Shunta Hakozaki, Atsushi Narumi, Takashi Kato, Masaru Tanaka, Kazuki Fukushima

Polymer Chemistry · 2022 · 16 citations · 24 references

DOIFull text

Open access

Concepts

Abstract

A cyclic carbonate with an ammonium carboxylate residue was found to serve as a nucleophile for esterification with alkyl bromides via the S N 2 mechanism.

References

24

Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters

Bas G. G. Lohmeijer, Russell C. Pratt, Frank A. Leibfarth et al. · Macromolecules · 2006 · 783 citations

, , +10

Blood compatible aspects of poly(2-methoxyethylacrylate) (PMEA)—relationship between protein adsorption and platelet adhesion on PMEA surface

Masaru Tanaka, Tadahiro Motomura, Miho Kawada et al. · Biomaterials · 2000 · 516 citations

, , +17

Synthesis, properties, and biodegradation of poly(1,3-trimethylene carbonate)

Kan Zhu, R. Wayne Hendren, Kasper Løvborg Jensen et al. · Macromolecules · 1991 · 488 citations

, , +12

Blood compatible materials: state of the art

Xiaoli Liu, Lin Yuan, Dan Li et al. · Journal of Materials Chemistry B · 2014 · 286 citations

, , +17

Tagging alcohols with cyclic carbonate: a versatile equivalent of (meth)acrylate for ring-opening polymerization

Russell C. Pratt, Fredrik Nederberg, Robert M. Waymouth et al. · Chemical Communications · 2007 · 238 citations

, , +12