Passivator-Free Microwave–Hydrothermal Synthesis of High Quantum Yield Carbon Dots for All-Carbon Fluorescent Nanocomposite Films

Abstract

Based on the self-passivation function of chitosan, an efficient, and green synthesis strategy was applied to prepare chitosan carbon dots (CDs). The quantum yield of carbon dots reached 35% under the conditions of hydrothermal temperature of 200 °C, hydrothermal time of 5 h, and chitosan concentration of 2%. Moreover, the obtained carbon dots had high selectivity and sensitivity to Fe³⁺. Based on the Schiff base reaction between the aldehyde groups of dialdehyde cellulose nanofibrils (DNF) and the amino groups of CDs, a chemically cross-linked, novel, fluorescent composite film, with high transparency and high strength, was created using one-pot processing. Knowing that the fluorescence effect of the composite film on Fe³⁺ had a linear relationship in the concentration range of 0-100 μM, a fluorescent probe can be developed for quantitative analysis and detection of Fe³⁺. Owing to their excellent fluorescent and mechanical properties, the fluorescent nanocomposite films have potential applications in the fields of Fe³⁺ detection, fluorescent labeling, and biosensing.