Interfacial tension driven adsorption of MnO₂ nanoparticles at the liquid/liquid interface to tailor ultra-thin polypyrrole sheets

Abstract

An emerging aspect of research is designing and developing fully tunable metamaterials for various applications with fluid interfaces. Liquid/liquid interface-assisted methods represent an efficient and facile route for synthesizing two-dimensional (2-D) thin films of potential materials. The underlying mechanism behind thin film formation at the liquid/liquid interface involves the preferential adsorption of nano-sized particles at the interface to minimize high interfacial tension. Here, a water/chloroform interface-assisted method is employed for the one-pot synthesis of highly crystalline polypyrrole/manganese dioxide (PPy/MnO₂) sheets. The temporal evolution in the dynamic interfacial tension (from 32 mN m^-1 to 17 mN m^-1) observed in pendant drop tensiometry proved the preferential adsorption of MnO₂ atttached PPy oligomers at the water/chloroform interface. An ultra-thin sheet-like morphology and uniform distribution of ∼6 nm highly crystalline MnO₂ nanoparticles are evidenced by transmission and atomic force microscopy techniques. The predominance of interfacial polymerization in retaining the electrochemical activity of the PPy/MnO₂ sheets is elucidated for the electrochemical detection of nicotine. This study opens a new avenue for the realization of ultra-thin sheets of polymer-nanomaterial hybrids, enabling applications ranging from new classes of sensors to optics.