Angewandte Chemie International Edition · 2022 · 35 citations · 48 references
Natural SciencesChemistryMaterials ScienceCatalysisInorganic ChemistryMaterials ChemistryCatalytic MaterialsCatalytic MechanismsMetal OxidesPerovskite MaterialsPorous MaterialsSelf-assemblyCatalytic Energy ConversionCo-assemblyLewis Acid CatalysisLewis AcidityMesoporous MaterialsModular AssemblyPerovskite OxidesPorous Catalysts
Abstract The ordered mesoporous perovskite oxides with well‐defined mesostrcture and versatile metal sites are attractive, but their successful synthesis faces challenges of complicated assembly dynamics and pore collapse in crystalline calcination. Here, we propose an energy balance concept to reveal interplay relationship in assembly process and realize regulation of porous structure for mesoporous perovskite oxides. A series of ordered mesoporous perovskite oxides with unique porous structure were prepared by a modular co‐assembly method. Mesoporous La 2 Zr 2 O 7 shows 94 % conversion and 99 % selectivity for hydrogenation of 5‐hydroxymethylfurfural (HMF) to 2,5‐bis(hydroxymethyl)furan. Experiments reveal that rich Lewis acid sites, active Zr species, and favorable porous structure promote interaction between mesoporous La 2 Zr 2 O 7 and HMF and reduce catalytic energy barrier. This work provides the insight into molecule co‐assembly and developing multiple component ordered mesoporous materials.
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