Effect of the Surface Modification of Silica Nanoparticles on the Viscosity and Mechanical Properties of Silica/Epoxy Nanocomposites

Abstract

Silica/epoxy hybrid resin has high viscosity owing to its particle size and aggregation in the epoxy matrix, which leads to poor usability and processability. To control the size of the silica nanoparticles, surface modification of the colloidal silica (12 nm) was conducted in two steps using a silane coupling agent. The silica nanoparticles were then dispersed in the epoxy resin using an amphiphilic solvent with a high boiling point instead of mechanical dispersion. A nanosilica/epoxy hybrid resin with a low viscosity was obtained. The hybrid resin containing 3 wt% silica nanoparticles obtained a viscosity value that is 1.2% that of the neat epoxy resin. The tensile and flexural strengths of the silica/epoxy nanocomposite, as well as the impact strength of the silica/epoxy nanocomposite, were improved by plastic deformation cause by the introduction of silica nanoparticles. With silica nanoparticles loading of 10 wt%, the tensile strength of the silica/epoxy nanocomposite increased by 24%, and the impact strength increased by 112%. For higher amounts of loaded silica nanoparticles, the tensile strength of the silica/epoxy nanocomposite continuously increased, while the impact strength decreased.