<i>In situ</i> synthesis of Cu‐doped ZIF‐8 for efficient photocatalytic water splitting

Abstract

Metal–organic frameworks (MOFs) reached a new level of research in photocatalysis by their virtue of tunable structure, modifiable pores, and a large surface area. Herein, we employed a simple metal ion exchange method to change ZIF‐8 from UV light to visible light absorption photocatalyst. In this work, Cu 2+ ions are integrated within the ZIF‐8 framework to synthesize Cu‐doped ZIF‐8 photocatalysts and well characterized by using both the spectroscopic and electrochemical studies. The Cu@ZIF‐8 (CDZ‐20) photocatalyst shows enhanced light‐harvesting ability and remarkable hydrogen generation rate of 13.9 mmolg −1 h −1 with an apparent quantum efficiency (AQE) of 9.08%, which is 17 times higher than that of pristine ZIF‐8 photocatalyst. The higher photocurrent density of 34 μA/cm 2 in CDZ‐20 further reinforced the superiority over the ZIF‐8 (1 μA/cm 2 ). This work paves the way to engineer robust copper doped ZIFs photocatalyst under mild synthesis approach for efficient H 2 evolution.