Synlett · 2022 · 31 citations · 79 references
Natural SciencesChemistryCatalysisInorganic ChemistryRedox BiochemistryCatalytic MechanismsChemical ReactionsCoordination ChemistryCross-coupling ReactionsReaction MechanismsRedox CatalysisC - C Coupling CatalysisC - C Coupling ReactionsCross CouplingOxidative CouplingRedox PropertiesTransition-metal-catalyzed Functionalization
Abstract In recent years, gold catalysis involving Au(I)/Au(III) redox cycle has gained significant attention. This account summarizes our contributions to the development of Au(I)/Au(III) catalysis, focusing on cross-coupling reactions and 1,2-difunctionalization reactions of C–C multiple bonds. A special emphasis has been given to understanding the mechanism of the reactions. 1 Introduction 2 Gold-Catalyzed Cross-Coupling Reactions 3 Gold-Catalyzed 1,2-Difunctionalization of C–C Multiple Bonds 4 Conclusion and Outlook
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