Crystal-field induced tuning of luminescence properties of Na<sub>3</sub>Ga<sub><i>x</i></sub>Al<sub>1−<i>x</i></sub>F<sub>6</sub>:Cr<sup>3+</sup> phosphors with good thermal stability for NIR LEDs

Jianbang Zhou, Pengyun Chen, Junhao Li, Mingming Yang, Wei Jiang, Qiuhong Zhang, Haiyong Ni, Jiansheng Huo

Dalton Transactions · 2022 · 19 citations · 34 references

Concepts

Abstract

exhibited high luminous efficiency and the emission intensity remained 81% at 423 K compared with the initial value at 298 K. The structural confinement and the electron-phonon coupling (EPC) effect may account for its good thermal stability. Finally, a pc-NIR-LED device with a photoelectric conversion efficiency of 6.53% at 350 mA was fabricated by combining the as-prepared NIR phosphor and a blue InGaN chip, and its applications in night vision and medical fields were further investigated. This work will promote the development of NIR phosphors with tunable luminescence properties.

References

34