Concepedia

Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C–H borylation of arenes

Takashi Komuro, Daiki Mochizuki, Hisako Hashimoto, Hiromi Tobita

Dalton Transactions · 2022 · 21 citations · 50 references

DOI

Concepts

Abstract

The synthesis of five-coordinate 16e SiNN-pincer complexes of iridium and rhodium, and catalytic C(sp 2 )–H borylation under mild conditions are described.

References

50

Synthesis, structure, and spectroscopic properties of copper(<scp>II</scp>) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(<scp>II</scp>) perchlorate

Anthony W. Addison, T. Nageswara Rao, J. Reedijk et al. · Journal of the Chemical Society Dalton Transactions · 1984 · 9.3K citations

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Mild Iridium-Catalyzed Borylation of Arenes. High Turnover Numbers, Room Temperature Reactions, and Isolation of a Potential Intermediate

Tatsuo Ishiyama, Jun Takagi, Kousaku Ishida et al. · Journal of the American Chemical Society · 2001 · 1.1K citations

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Remarkably Selective Iridium Catalysts for the Elaboration of Aromatic C-H Bonds

Jian-Yang Cho, Man Kin Tse, Daniel Holmes et al. · Science · 2002 · 1.1K citations

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Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

John F. Hartwig · Accounts of Chemical Research · 2011 · 1.1K citations

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Mechanism of the Mild Functionalization of Arenes by Diboron Reagents Catalyzed by Iridium Complexes. Intermediacy and Chemistry of Bipyridine-Ligated Iridium Trisboryl Complexes

Timothy M. Boller, Jaclyn M. Murphy, Marko Hapke et al. · Journal of the American Chemical Society · 2005 · 529 citations

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