Facile Electrodeposition of NiCo2O4 Nanosheets on Porous Carbonized Wood for Wood-Derived Asymmetric Supercapacitors

Abstract

Multichannel-porous carbon derived from wood can serve as a conductive substrate for fast charge transfer and ion diffusion, supporting the high-theory capacitance of pseudocapacitive materials. Herein, NiCo₂O₄ nanosheets, which are hierarchically porous, anchored on the surface of carbonized wood via electrodeposition for free-binder high-performance supercapacitor electrode materials, were proposed. Benefiting from the effectively alleviated NiCo₂O₄ nanosheets accumulation and sufficient active surface area for redox reaction, a N-doped wood-derived porous carbon-NiCo₂O₄ nanosheet hybrid material (NCNS-NCW) electrode exhibited a specific electric capacity of 1730 F g^-1 at 1 A g^-1 in 1 mol L^-1 KOH and splendid electrochemical firmness with 80% capacitance retention after cycles. Furthermore, an all-wood-based asymmetric supercapacitor based on NCNS-NCW//NCW was assembled and a high energy density of 56.1 Wh kg^-1 at a watt density of 349 W kg^-1 was achieved. Due to the great electrochemical performance of NCNS-NCW, we expect it to be used as an electrode material with great promise for energy storage equipment.