Slow magnetic relaxation in a Dy₃ triangle and a bistriangular Dy₆ cluster

Abstract

Two lanthanide single-molecule magnets (SMMs) [Dy₃(μ₃-OH)(HL-1)₃(H₂O)₃](NO₃)₂·3H₃O (1, H₃L-1 = (<i>E</i>)-3-(((8-hydroxyquinolin-2-yl)methylene)amino)propane-1,2-diol) and [Dy₆(μ₃-OH)₄(H₂L-2)₄(HL-2)₂(L-2)₂] (2, H₃L-2 = (<i>E</i>)-2-hydroxy-<i>N</i>'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide) were synthesized and characterized structurally and magnetically. Complex 1 contains a triangular Dy₃ core in which the three Dy³⁺ ions share a μ₃-OH^- anion and the deprotonated ligands of (HL-1)^2- serve both capping and bridging functions, while 2 displays a centrosymmetric hexanuclear Dy^III structure with two similar Dy₃ triangular cores ligated by two fully deprotonated (L-2)^3- ligands, each of which shares two μ₃-OH^- anions. All the Dy^III ions are eight-coordinated with quasi <i>D</i>_2d or <i>C</i>_2v symmetry. Magnetic studies reveal that 1 exhibited two-step magnetic relaxation under an applied dc field of 800 Oe, with effective energy barriers of 40.1 and 31.0 K for the slow relaxation (SR) and fast relaxation regimes (FR), respectively. Meanwhile, 2 only showed a tail of slow magnetic relaxation at above 2 K. <i>Ab initio</i> calculations have been carried out to show the nature of their different magnetic properties.