Nature Communications · 2022 · 117 citations · 73 references
Natural SciencesChemistryMedicinal ChemistryCatalysisGreen ChemistryOrganic ChemistryCarboxylic AcidsCatalytic MechanismsOrganic SynthesisPhotocatalysisPhotochemistryRadical ReactionsCarboxylic Acid Derivative SynthesisCarboxylic Acid SynthesisDecarboxylative CouplingHeterocyclic CatalysisKetonesMild Reaction ConditionsPhotocatalytic Heterocycle SynthesisPhotocatalytic Synthesis
The carbene and photocatalyst co-catalyzed radical coupling of acyl electrophile and a radical precursor is emerging as attractive method for ketone synthesis. However, previous reports mainly limited to prefunctionalized radical precursors and two-component coupling. Herein, an N-heterocyclic carbene and photocatalyst catalyzed decarboxylative radical coupling of carboxylic acids and acyl imidazoles is disclosed, in which the carboxylic acids are directly used as radical precursors. The acyl imidazoles could also be generated in situ by reaction of a carboxylic acid with CDI thus furnishing a formally decarboxylative coupling of two carboxylic acids. In addition, the reaction is successfully extended to three-component coupling by using alkene as a third coupling partner via a radical relay process. The mild conditions, operational simplicity, and use of carboxylic acids as the reacting partners make our method a powerful strategy for construction of complex ketones from readily available starting materials, and late-stage modification of natural products and medicines.
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An overview of N-heterocyclic carbenes
Matthew N. Hopkinson, Christian Richter, Michael Schedler et al. · Nature · 2014 · 4.2K citations
Zhiwei Zuo, Derek T. Ahneman, Lingling Chu et al. · Science · 2014 · 1.6K citations · Full text