The Levels and Sources of Nitrous Acid (HONO) in Winter of Beijing and Sanmenxia

Abstract

Abstract HONO concentrations in Beijing (BJ) and Sanmenxia (SMX) were simultaneously measured in winter with a duration of 1 month, and the sources and sinks of HONO in the two cities were comparably analyzed. BJ and SMX had different pollution characteristics. Direct vehicle emission made a contribution to observed HONO of about 28% in BJ, whereas it contributed to HONO only about 12% in SMX. Additionally, direct emission from coal combustion in SMX also made a significant contribution to atmospheric HONO, which could achieve to be 13%. In BJ, nighttime NO 2 conversion on the aerosol and ground surfaces contributed to HONO sources of 15% and 27%, respectively. In SMX, nighttime NO 2 conversion on the aerosol and ground surfaces contributed to HONO sources of 40% and 30%, respectively. Daytime NO 2 heterogeneous conversion (including photo‐enhanced conversion) on the aerosol and ground surfaces was important in SMX. Daytime NO 3 − photolysis contributed 9% HONO in SMX and 4% in BJ. The primary OH production rates from photolysis of daytime HONO in both BJ and SMX were three orders of magnitude faster than those from photolysis of O 3 , revealing the dominant role of HONO in local atmospheric chemistry of the two cities in winter.