Iron Carbonate Scale Growth and the Effect of Inhibition in CO2 Corrosion of Mild Steel

Abstract

Abstract Investigations were conducted to investigate iron carbonate scale precipitation, the interaction between a corrosion inhibition and the precipitating iron carbonate scale, and their effects on the corrosion rate. Both the effects of iron carbonate precipitation on inhibited and uninhibited surfaces and the effects of inhibition on surfaces with iron carbonate scale were studied. The experiments were done in glass cells at 80 °C and a iron carbonate supersaturation range of 7 – 150. A generic imidazoline based inhibitor was added at various points in the iron carbonate scale formation process. Both corrosion rates and precipitation rates were measured using electrochemical and weight gain/loss methods. The scale was later analyzed using scanning electron microscopy (SEM). It was found that the dissolved ferrous ion concentration method, used previously, overestimates the rate of iron carbonate precipitation. Although no antagonism was found under any of other conditions tested, it was seen that the addition of the inhibitor retarded the growth of the iron carbonate scale.