Natural SciencesEarth SciencesGeologyGeochemistryPetrologyVolcanologyCarbonate MineralsMagma EvolutionMineral GeochemistryVolcanic GeochemistryVolcanic PetrologyVolcanic RocksCarbonatite MineralizationFluid Inclusion GeochemistryIsotopic Abundance RatiosIsotopic Line RatiosIsotopic RatiosMagma ChemistryMagmatic GeochemistryRare Earth Element Mineralization
Abstract Normal carbonatite magmas are characteristically associated with ijolites and produce extensive fenitization by alkali metasomatism, commonly feldspathization or phlogopitization. The sequence of carbonatites developed from this magma are characterized by igneous isotopic ratios, high contents of incompatible elements, their distinctive pattern of differentiation from sövite to beforsite, and a late-stage rare-earth element, baryte, fluorite mineralization. Carbonatite rock is composed mainly of calcite, but fluid inclusion and related data indicate that the original magma was highly alkaline and chemically similar to that known at Oldoinyo Lengai volcano in Tanzania. It is suggested that this carbonatite magma is secondary magma produced from carbonated nephelinite magma by liquid immiscibility. Carbonatite magma can also occur associated with kimberlites but these carbonatites are alkali-poor and do not produce the characteristic fenitization.
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W. S. Fyfe · Tectonophysics · 1968 · 906 citations
Alkali ion exchange between vapor and feldspar phases
Philip M. Orville · American Journal of Science · 1963 · 423 citations
The System CaO-CO2-H2O and the Origin of Carbonatites
Peter J. Wyllie, O. F. Tuttle · Journal of Petrology · 1960 · 307 citations