Journal of The Electrochemical Society · 1956 · 32 citations · 0 references
Natural SciencesChemistryInorganic ChemistryNuclear ChemistryPhysical ChemistryChemical ThermodynamicsGas-phase Reaction KineticsNuclear ReactionsHydride FormationHydride Transfer ChemistryHydride Transfer ProcessesHydrogen ChemistryLinear Rate LawNuclear Reaction RatesThermonuclear Reaction RatesUranium Chemistry
The reaction of hydrogen with uranium to produce uranium hydride was studied in the temperature range 96°–400°C at pressure levels of of mercury (where is system pressure and is the plateau dissociation pressure of the uranium hydride product). Reaction rates followed the linear law. At a given , the linear rate increased with increasing temperature in the range 96° to about 250°C and decreased with increasing temperature from about 250° to 400°C. Variation of the linear rate with temperature and pressure in the range 96° to about 250°C is given by the equation: