Continuous Rhodium‐Catalyzed Hydroformylation of 1‐Octene with Polyhedral Oligomeric Silsesquioxanes (POSS) Enlarged Triphenylphosphine

Abstract

Ausdauernder Katalysator: Die homogenkatalysierte Aldehydsynthese in einem Flussreaktor mit Nanofiltration kann bis zu zwei Wochen ohne Anzeichen für sonst übliche Katalysatordesaktivierung oder -verluste betrieben werden. Als Ligand des wiederverwendbaren, hoch aktiven und selektiven Katalysators dient ein robustes starres PPh3-Derivat mit sperrigen Silsesquioxan-Einheiten. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.