Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High‐Molecular‐Weight, Helically Chiral Polyquinoxaline‐Based Phosphines

Abstract

Katalytische Spirale: In Gegenwart helical-chiraler Polychinoxalin-basierter Phosphane (PQXphos) mit hohem Molekulargewicht gelingen hoch enantioselektive Suzuki-Miyaura-Kupplungen von 1-Brom-2-naphthalinphosphonsäureestern mit o-Methylphenylboronsäuren. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.