Hydrogen‐Bond‐Promoted Palladium Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3‐Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands

Abstract

Unsymmetrisch/asymmetrisch: Neuartige chirale BiSO-P-Liganden erwiesen sich als wirksam in der Palladium-katalysierten asymmetrischen allylischen Alkylierung von Indolen mit den racemischen Titel-Acetaten durch dynamische kinetische asymmetrische Transformation (DYKAT). Die gebildete Wasserstoffbrücke zwischen der Sulfinylgruppe des Liganden und dem Indol-NH spielt eine wichtige Rolle in der Reaktion. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.