One‐Pot Ring‐Closing Metathesis/1,3‐Dipolar Cycloaddition through Assisted Tandem Ruthenium Catalysis: Synthesis of a Dye with Isoindolo[2,1‐<i>a</i>]quinoline Structure

Mitsuhiro Arisawa, Yuki Fujii, Hiroshige Kato, Hayato Fukuda, Takashi Matsumoto, Mika Ito, Hiroshi Abe, Yoshihiro Ito, Satoshi Shuto

Angewandte Chemie · 2012 · 12 citations · 31 references

Concepts

Abstract

Die Eintopf-Tandemreaktion von N-Alkyl-N-allyl-2-vinylanilin-Derivaten mit Benzo- oder Naphthochinonen und einem Ruthenium-Alkyliden-Katalysator führt zu Isoindolo[2,1-a]chinolinen (siehe Schema), deren Farben durch Austausch der Substituenten am heterocyclischen Kern verändert werden können. Die Reaktion bietet eine neue Methode zur Synthese π-konjugierter kleiner Moleküle aus einfachen Anilin-Derivaten. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

31