Atmospheric Evolution of Molecular Weight Separated Brown Carbon from Biomass Burning

Abstract

Abstract. Biomass burning is a major source of atmospheric brown carbon (BrC) and through its absorption of UV/VIS radiation, it can play an important role on the planetary radiative balance and atmospheric photochemistry. The considerable uncertainty of BrC impacts is associated with its poorly constrained sources, transformations and atmospheric lifetime. Here we report laboratory experiments that examined changes in the optical properties of the water-soluble BrC fraction of biomass burning particles. Effects of direct UVB photolysis and OH oxidation in the aqueous phase on molecular weight-separated BrC were studied. Results indicated that low molecular weight (MW) BrC ( 10 hours) biomass burning emissions, poor linear correlations were found between light absorptivity and levoglucosan, consistent with other studies suggesting a short atmospheric lifetime for levoglucosan. However, a much stronger correlation between light absorptivity and total hydrous sugars was observed, suggesting that they may serve as more robust tracers for aged biomass burning emissions. Overall, the results from this study suggest that robust model estimates of BrC radiative impacts require consideration of the atmospheric aging of BrC and the stability of high-MW BrC.