Metal–Silicon Triple Bonds: Nucleophilic Addition and Redox Reactions of the Silylidyne Complex [Cp(CO)₂MoSi‐R]

Abstract

Als Silicium-Variante der Metallalkylidin-Komplexe bietet die Titelverbindung neue Perspektiven für die Organosiliciumchemie. Das Synthesepotenzial von 1 wird an einer Serie von Reaktionen gezeigt, die Zugang zu den ersten anionischen Silyliden-Komplexen und dianionischen Silyl-Komplexen bieten (siehe Schema; Nu= Cl, N3, CH3; R=C6H3-2,6-Trip2). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.