Demonstration of Chemisorption of Carbon Dioxide in 1,3‐Dialkylimidazolium Acetate Ionic Liquids

Gabriela Gurău, Héctor Rodríguez, Steven P. Kelley, Peter Janiczek, Roland Kalb, Robin D. Rogers

Angewandte Chemie · 2011 · 75 citations · 17 references

Concepts

Abstract

Echte Chemie: Spektroskopische und kristallographische Analysen bestätigen die chemische Reaktion von CO2 mit Carbenen in flüssigen 1,3-Dialkylimidazoliumacetaten sowie die unterstützende Rolle des Acetations in diesen Reaktionen. Wenn CO2 durch [C2mim][OAc] geleitet wurde, konnte die Bildung des entsprechenden Imidazoliumcarboxylats, [C2mim+-COO−], beobachtet werden. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

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