Enantioselective Palladium(II) Phosphate Catalyzed Three‐Component Reactions of Pyrrole, Diazoesters, and Imines

Abstract

Reaktionstrio: Die Titelreaktion ergibt C-H-funktionalisierte Pyrrolderivate in mäßigen bis guten Ausbeuten; sowohl die syn- als auch die anti-Produkte mit zwei benachbarten Stereozentren sind mit guten Regio-, Diastereo- und Enantioselektivitäten zugänglich. Der Prozess ist die erste hoch enantioselektive Palladiumcarbenoid-vermittelte Reaktion. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.