Rhodium(III)‐Catalyzed Alkenyl CH Bond Functionalization: Convergent Synthesis of Furans and Pyrroles

Abstract

Biologisch wichtige substituierte Furane und Pyrrole werden effizient durch die RhIII-katalysierte Reaktion von α,β-ungesättigten O-Methyloximen mit Aldehyden und N-Tosyliminen erhalten. Die zunächst gebildeten intermediären sekundären Alkohole bzw. Amine cyclisieren unter den Reaktionsbedingungen in guten Ausbeuten unter Aromatisierung zu den Produkten. Cp*=C5Me5, DCE=1,2-Dichlorethan, THF=Tetrahydrofuran. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.