A Chiral‐Anion Generator: Application to Catalytic Desilylative Kinetic Resolution of Silyl‐Protected Secondary Alcohols

Abstract

Fluorid fest im Griff: Chirale hydroxyterminierte Polyether mit 3,3′-halogensubstituierten chiralen Binolgruppen dienen als ein neuartiges Strukturmotiv für die Generierung chiraler Anionen. Die einzigartigen Eigenschaften dieser Reagentien zeigen sich in der hoch enantioselektiven desilylierenden kinetischen Racematspaltung silylgeschützter racemischer Alkohole mit KF (siehe Schema). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.