Copper/Palladium‐Catalyzed 1,4 Reduction and Asymmetric Allylic Alkylation of α,β‐Unsaturated Ketones: Enantioselective Dual Catalysis

Abstract

Vereinte Kräfte: Die Kupplung zweier metallorganischer Intermediate gelingt über eine duale Cu/Pd-Katalyse (siehe Schema, LG=Abgangsgruppe), bei der CuI katalytisch das Ausgangsmaterial für den Pd0-Katalysezyklus bereitstellt. Obwohl die Reagentien in stöchiometrischen Mengen in der Reaktionsmischung vorhanden sind und beide aktiven Intermediate abfangen könnten, verläuft die erwünschte Reaktion wie geplant. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.