Synthesis of ZIF‐8 and ZIF‐67 by Steam‐Assisted Conversion and an Investigation of Their Tribological Behaviors

Abstract

Unter Volldampf: H2O als Reaktionsmedium in einer konventionellen Hydrothermalsynthese ergibt zwei unporöse Materialien mit dichten dia-Netzwerken, dia(Zn) und dia(Co), aus 2-Methylimidazol und M(OAc)2 (M=Zn, Co; linke Strukturen). Trennung des Wassers und einer festen Mischung derselben Startmaterialien in einer dampfunterstützten Umwandlung liefert hingegen zwei poröse Materialien mit offenen Gerüsten, ZIF-8 und ZIF-67 (rechts). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.