Enantioselective Palladium‐Catalyzed Decarboxylative Allylation of Carbazolones: Total Synthesis of (−)‐Aspidospermidine and (+)‐Kopsihainanine A

Abstract

Funktionalisierte chirale Carbazolone mit α-quartären Kohlenstoffzentren werden durch Ligand-kontrollierte Pd-katalysierte enantioselektive decarboxylierende allylische Alkylierung von Carbazolonen hergestellt (siehe Schema). Diese katalytische asymmetrische Reaktion wurde als Schlüsselschritt in der Totalsynthese von Aspidospermidin und (+)-Kopsihainanin A genutzt. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.