A Room‐Temperature X‐ray‐Induced Photochromic Material for X‐ray Detection

Ming‐Sheng Wang, Yang Chen, Guan‐E Wang, Gang Xu, Xiangying Lv, Zhong‐Ning Xu, Rong‐Guang Lin, Li‐Zhen Cai, Guo‐Cong Guo

Angewandte Chemie International Edition · 2012 · 186 citations · 18 references

Concepts

Abstract

A color change: X-ray-induced photochromic species are rare and can be used for detection of X-rays. A highly robust X-ray-sensitive material with the discrete structure of a metal–organic complex has been found to show both soft and hard X-ray-induced photochromism at room temperature (see picture). A new ligand-to-ligand electron-transfer mechanism was proposed to elucidate this photochromic phenomenon. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

18