Angewandte Chemie International Edition · 2012 · 186 citations · 18 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryOptical MaterialsRadiation DetectionPhotochemistryPhotochromic MaterialsRadiation ChemistryX-ray DetectionX-ray DetectorsX-ray SpectroscopyPhotoactive Metal ComplexesSoft X-ray OpticsSoft X-ray SpectroscopyX-ray Absorption Spectroscopy
A color change: X-ray-induced photochromic species are rare and can be used for detection of X-rays. A highly robust X-ray-sensitive material with the discrete structure of a metal–organic complex has been found to show both soft and hard X-ray-induced photochromism at room temperature (see picture). A new ligand-to-ligand electron-transfer mechanism was proposed to elucidate this photochromic phenomenon. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Organic photochromism (IUPAC Technical Report)
Henri Bouas‐Laurent, Heinz Dürr · Pure and Applied Chemistry · 2001 · 933 citations · Full text
An X-ray-induced insulator–metal transition in a magnetoresistive manganite
V. Kiryukhin, D. Casa, J. P. Hill et al. · Nature · 1997 · 475 citations
Natural Sciences, Materials Engineering, Materials Science +14