Copper‐Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates

Abstract

Defluorierung: Unter Kupferkatalyse können C-F-Bindungen effizient aktiviert und durch C-H-Bindungen ersetzt werden. Auf der Grundlage von experimentellen und theoretischen Studien wird ein Kupferhydrid als aktive Zwischenstufe vorgeschlagen, die den Fluorkohlenstoff nucleophil angreift (siehe Struktur; C grau, H weiß, Cu hellrot, F hellblau; Abstände in Å). As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.