Regio‐ and Enantioselective Hydroamination of Dienes by Gold(I)/Menthol Cooperative Catalysis

Abstract

Mit Alkohol geht's besser: Geschwindigkeit und Selektivität der regio- und enantioselektiven Hydroaminierungen von 1,3-Dienen in Gegenwart des Digoldkomplexes (R)-DTBM-SEGPHOS werden durch Zusatz von Alkoholen wie Menthol gesteigert. Durch Koordination an Gold(I)-Kationen entsteht eine Brønsted-Säure, die in die Katalyse eingreift. Mbs=p-Methoxybenzolsulfonyl. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.