A Rhodium Peroxido Complex in Mono‐, Di‐, and Peroxygenation Reactions

Abstract

Der vielseitige Rhodiumperoxidokomplex 1, der durch Einwirkung von Disauerstoff auf 2 erzeugt werden kann, vermittelt die Monooxygenierung eines Phosphans zu Phosphinoxid und die Dioxygenierung von Tetrakis(dimethylamino)ethylen zum Harnstoffderivat. Die Umwandlung von 9,10-Dimethylanthracen in das Endoperoxid verläuft in Gegenwart von Disauerstoff bereits mit substöchiometrischen Mengen an 1 (siehe Schema). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.