A Polymer‐Supported Chiral Dirhodium(II) Complex: Highly Durable and Recyclable Catalyst for Asymmetric Intramolecular CH Insertion Reactions

Abstract

Eine sehr effektive Immobilisierung von [Rh2(S-PTTL)4] (PTTL=N-Phthaloyl-tert-leucinat) gelang durch Copolymerisation des Monomers 1 mit Styrol und einem flexiblen Vernetzer. Der immobilisierte Katalysator ermöglicht die Titelreaktion bei −78 °C mit hoher Enantioselektivität und konnte für 100 Zyklen bei geringem Auswaschen (0.28 ppm) genutzt werden. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.