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Dioxygen Activation by a Mononuclear IrII–Ethene Complex
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2002
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Inorganic ChemistryChemical EngineeringEngineeringDioxygen ActivationHöhere OxidationsstufeNatural SciencesCoordination ComplexMolecular BiologyOrganic ChemistryMolecular ComplexRedox ChemistryChemistryMit Disauerstoff ZuDeoxygenationDer Erste IridiumInorganic Compound
Aktivierung erfordert höhere Oxidationsstufe: Der erste Iridium(II)-Ethen-Komplex, 2, wurde durch Einelektronenoxidation des entsprechenden IrI-Komplexes 1 erhalten. Während 1 mit Disauerstoff zu einem IrIII-Peroxo-Ethen-Komplex reagiert, aktiviert 2 Disauerstoff, und es entsteht der Formylmethyl-Komplex 3. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2002/z18624_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.