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Regiospecific Construction of Polyoxygenated 9,10-Anthraquinones. Total Synthesis of Islandicin and Digitopurpone
10
Citations
5
References
1973
Year
Bioorganic ChemistryEngineeringSynthetic PhotochemistryOrganic ChemistryChemistryMedicinal ChemistryBiosynthesisDiversity Oriented SynthesisNatural Coloring MattersNatural Product BiosynthesisAntibiotic Adriamycin4 1PhotochemistryDiversity-oriented SynthesisTotal SynthesisNatural Product SynthesisRegiospecific ConstructionBiomolecular EngineeringFriedel-crafts6 ApproachesNatural SciencesPolyoxygenated 9,10-AnthraquinonesSynthetic Chemistry
Abstract Current interest3 in a practical synthesis of the antibiotic adriamycin4 1 prompts us to report some consequences of the photochemical5 versus the Friedel-Crafts6 approaches in the construction of unsymmetrical polyhydroxy-anthraquinones. These two complementary methods have now been exploited in the preparation of the natural coloring matters islandicin,7 2, and digitopurpone,8 3.
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