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Developments in Pd Catalysis: Synthesis of 1<i>H</i>‐1,2,3‐Triazoles from Sodium Azide and Alkenyl Bromides
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Citations
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2006
Year
EngineeringPd CatalysisOrganic ChemistryChemistryAlkenyl BromidesHeterocycle ChemistrySodium AzidePharmaceutical ChemistryChemical DerivativeChemical EngineeringMedicinal ChemistryOrganometallic CatalysisBiochemistryPd0-xantphos-katalysators DirektCatalysisSiehe SchemaPharmacologyAsymmetric CatalysisHeterocyclicNatural SciencesDerivative (Chemistry)Alkenylbromiden Und NatriumazidDrug Discovery
Neues von Altbekanntem: Immer noch lassen sich Reaktionen finden, die von den allgegenwärtigen Pd0-Katalysatoren unterstützt werden. So entstehen 1H-1,2,3-Triazole in Gegenwart eines Pd0-Xantphos-Katalysators direkt aus Alkenylbromiden und Natriumazid (siehe Schema, Xantphos=9,9-Dimethyl-4,5-bis(diphenylphosphanyl)xanthen, dba=trans,trans-Dibenzylidenaceton). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z601045_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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