Mechanism of Formation of Palladium Nanoparticles: Lewis Base Assisted, Low‐Temperature Preparation of Monodisperse Nanoparticles

Abstract

Leichter geht's mit Base: Die Bildung aminbedeckter Pd-Nanopartikel aus [Pd(acac)2] (acac=Acetylacetonat) verläuft über Pd-Amido- und Pd-Hydrid-Zwischenstufen. Durch Zusatz einer Lewis-Base kann die Reaktionstemperatur für die Synthese monodisperser Nanopartikel deutlich gesenkt werden. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.