Ligand Passivated Core–Shell FePt@Co Nanomagnets Exhibiting Enhanced Energy Product

David J. Carnevale, Michael Shatruk, Geoffrey F. Strouse

Chemistry of Materials · 2016 · 26 citations · 38 references

Concepts

Abstract

Systematic growth of a soft-magnet Co shell (0.6 to 2.7 nm thick) around a hard-magnet Fe 0.65 Pt 0.35 core (5 nm in diameter) has been achieved in a one-pot microwave synthesis. This controlled growth led to a 4-fold enhancement in the energy product of the core–shell assembly as compared to the energy product of bare Fe 0.65 Pt 0.35 nanoparticles. The simultaneous enhancement of coercivity and saturation moment reflects the onset of theoretically predicted exchange-spring behavior. The demonstration of nanoscale exchange-spring magnets can lead to improved high-performance magnet design for energy applications.

References

38