Publication | Closed Access
Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (−)‐Spiroxin C
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Citations
27
References
2017
Year
DerivativesEngineeringBiochemistryPhotochemistry‐Spiroxin CIntramolecular Photoredox ReactionsNaphthoquinone DerivativesStereospecific MannerNatural SciencesMechanistic PhotochemistrySynthetic PhotochemistryOrganic ChemistryEnantioselective Total SynthesisChemistryPharmacologyBiomolecular EngineeringPhotoredox Process
Abstract Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (−)‐spiroxin C.
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