Die Angewandte Makromolekulare Chemie · 1982 · 10 citations · 1 references
Natural SciencesChemical EngineeringChemistryPolymer ChemistryPolymer EngineeringPolymer MaterialsPolymer ProcessingPolymer SynthesisPolymerization ChemistryPolymerization KineticsPolymerization ProcessesPolymerization Temperature EffectsActivation EnergyApparent Activation EnergyCopolymerizationCopolymerization KineticsPolymerization MechanismsTemperature DependenceTemperature Dependence Of PolymerizationThermal Activation Of Polymerization
Abstract The copolymerization of 6‐caprolactam with 12‐dodecanelactam with 2 mol‐% 6‐aminocaproic acid as the initiator was investigated at 260°C within a broad concentration range of both comonomers. With increasing content of 12‐dodecanelactam in the initial mixture the equilibrium content of the copolymer increased and the rate of copolymerization decreased. In the initial stage of copolymerization 12‐dodecanelactam disappeared very quickly from the initial mixture; it was not incorporated into the copolymer directly, but through oligomers, probably through a cyclic dimer. The effect of temperature on the copolymerization process was examined for an equimolar composition of the initial mixture. It was demonstrated that starting with the polymerization temperature of 260°C, the copolymers underwent degradation on long‐termin heating. At 280°C, degradation occured already after 50 h of polymerization. The apparent activation energy of copolymerization, 62 kJ/mol, was calculated from the temperature dependence.
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