Tetrakis(arylisocyanide) Rhodium(I) Salts in Water: NIR Luminescent and Conductive Supramolecular Polymeric Nanowires with Hierarchical Organization

Abstract

Rausziehen, rausziehen! Amphiphile Tetrakis(2,6-xylylisocyanid)rhodium(I)-Komplexe organisieren sich in Wasser über RhI⋅⋅⋅RhI- und hydrophobe Wechselwirkungen unter Bildung sehr langer kristalliner Nanodrähte in hierarchische Mikro- und Makrostrukturen. Die auf diesem Weg aus Lösungen erhaltenen metallorganischen Überstrukturen lumineszieren im Nahinfrarot und sind elektrische Leiter. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.