Enantioselective Synthesis and Stereoselective Ring Opening of <i>N</i>‐Acylaziridines

Abstract

Die kinetische Racematspaltung von N-Acylaziridinen gelingt durch nucleophile Ringöffnung mit (R)-BINOL als chiralem Modifikator unter Bor-katalysierten Bedingungen (siehe Schema; Ar=3,5-Dinitrophenyl). Das verbrauchte Enantiomer des Aziridins kann zu einem enantiomerenangereicherten 1,2-Chloramid weiter umgesetzt werden, und (R)-BINOL wird zurückgewonnen. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.