Regiospecific Ligand Oxygenation in Iron Complexes of a Carboxylate‐Containing Ligand Mediated by a Proposed Fe^V–Oxo Species

Abstract

Nachgeahmt: Durch biomimetische Peroxid-Aktivierung (H2O2 oder tBuOOH) können die gezeigten N4O-Liganden in Komplexen mit Eisen(III) entweder an einem aromatischen Kohlenstoffatom oder an einem aliphatischen Stickstoffatom selektiv oxygeniert werden. Supporting information for this article (syntheses and characterizations, full details of single-crystal X-ray analyses, list of structures considered for definition of average NO bond distance in coordinated N-oxides, ESI MS of 5-FeCl4⋅H2O and the N-oxygenation reaction mixture in H2O) is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z502656_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.