Concepedia

<i>Ansa</i>‐Cycloheptatrienyl–Cyclopentadienyl Complexes

Matthias Tamm, A. Kunst, Thomas Bannenberg, Eberhardt Herdtweck, Peter Sirsch, Cornelis J. Elsevier, Jan Meine Ernsting

Angewandte Chemie · 2004 · 48 citations · 32 references

DOI

Concepts

Abstract

Die Einführung der Me2Si-Brücke und die Verzerrung der Sandwichstruktur erleichtern die Wechselwirkung des 16-Elektronen-ansa-Komplexes (siehe Bild; blau Ti, gelb Si, grau C) mit σ-Donor/π-Acceptorliganden wie CO oder Isocyaniden. Dadurch gelang es, die elektronische Struktur dieses stark gebogenen ersten ansa-Cycloheptatrienyl-Cyclopentadienyl-Übergangsmetallkomplexes zu untersuchen. Der Komplex wurde aus [(η-C7H7)Ti(η-C5H5)] erhalten. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2004/z460538_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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