Palladium‐Catalyzed Dehydrative Heck Olefination of Secondary Aryl Alcohols in Ionic Liquids: Towards a Waste‐Free Strategy for Tandem Synthesis of Stilbenoids

Rakesh Kumar, Amit Shard, Richa Bharti, Yogesh Thopate, Arun K. Sinha

Angewandte Chemie · 2012 · 18 citations · 30 references

Concepts

Abstract

Alles in einem: Eine Tandemstrategie wurde entwickelt, mit der sekundäre Arylalkohole direkt mit Arylhalogeniden gekuppelt wurden. Die Reaktion liefert Stilbenoide über eine dehydratisierende Heck-Sequenz in der ionischen Flüssigkeit [hmim]Br unter Mikrowellenbestrahlung (siehe Schema). hmim= 1-n-Hexyl-3-methylimidazolium. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

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