Acta Crystallographica Section E Structure Reports Online · 2010 · 10 citations · 2 references
Natural SciencesBiochemistryChemistryCrystal StructureInorganic ChemistryOrganic ChemistryCoordination ChemistryMetal OxidesMetal SulfidesMetal-ligand BondingMolecular SymmetryTransition Metal ComplexesCrystal Structures Of Metal SulfidesCrystallographic SymmetryCrystallographic Symmetry AnalysisMetal Sulfide Coordination ChemistrySite Symmetry EffectsTransition Metal Sulfides
In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(2+) ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O'-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO(2)N(4) octa-hedral geometry for the metal ion. The complete propane-1,3-diol mol-ecule is generated by crystallographic twofold symmetry and two O-H⋯O hydrogen bonds are formed with the uncoordinated O atoms of the sulfate group.
2
A short history of<i>SHELX</i>
George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 2007 · 87.4K citations · Full text