Concepedia

Copper‐Catalyzed Intramolecular Electrophilic Carbofunctionalization of Allylic Amides

Elise Cahard, Nadine Bremeyer, Matthew J. Gaunt

Angewandte Chemie · 2013 · 35 citations · 68 references

DOI

Concepts

Abstract

Eine­ endo-selektive kupferkatalysierte Oxyarylierung oder Oxyvinylierung von Allylamiden liefert ausschließlich die anti-Isomere von Oxazin-Sechsringen. Vielfältig substituierte Allylamide und Diaryliodonium- sowie Vinyl(aryl)iodoniumtriflate gehen diese Umwandlung ein.

References

68

A Meta-Selective Copper-Catalyzed C–H Bond Arylation

Robert J. Phipps, Matthew J. Gaunt · Science · 2009 · 988 citations

, , +14

Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions

Robert J. Phipps, Neil P. Grimster, Matthew J. Gaunt · Journal of the American Chemical Society · 2008 · 793 citations

, , +12

Oxidative C−H Activation/C−C Bond Forming Reactions:  Synthetic Scope and Mechanistic Insights

Dipannita Kalyani, Nicholas R. Deprez, Lopa V. Desai et al. · Journal of the American Chemical Society · 2005 · 792 citations

, , +16

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

John F. Hartwig, Levi M. Stanley · Accounts of Chemical Research · 2010 · 711 citations

, , +16

Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

Basudev Sahoo, Matthew N. Hopkinson, Frank Glorius · Journal of the American Chemical Society · 2013 · 535 citations

, , +14